期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 42, 页码 14678-14693出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502005
关键词
C-C coupling; C-H activation; hypervalent iodine; metal-free; oxidative coupling
资金
- Max-Planck-Gesellschaft
The formation of C-C bonds embodies the core of organic chemistry because of its fundamental application in generation of molecular diversity and complexity. C-C bond-forming reactions are well-known challenges. To achieve this goal through direct functionalization of C-H bonds in both of the coupling partners represents the state-of-the-art in organic synthesis. Oxidative C-C bond formation obviates the need for prefunctionalization of both substrates. This Minire-view is dedicated to the field of C-C bond-forming reactions through direct C-H bond functionalization under completely metal-free oxidative conditions. Selected important developments in this area have been summarized with representative examples and discussions on their reaction mechanisms.
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