期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 40, 页码 13930-13933出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502425
关键词
alkynes; borylation; organocatalysis; photochemistry; sulfides
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [26620149]
- Grants-in-Aid for Scientific Research [26620149] Funding Source: KAKEN
An efficient metal-free diboration of terminal alkynes is reported. In the presence of a catalytic amount of organosulfides under light, the addition of bis(pinacolato)-diboron (B(2)pin(2)) to terminal alkynes takes place efficiently to produce the corresponding double borylation products in good yields. Mechanistic studies indicate that this metal-free sulfide-catalyzed diboration of alkynes likely occurs by generation of a boryl-centered radical with the aid of light and a sulfide, since such a radical was detected in the reaction mixture by electron spin resonance (ESR) spectroscopy. The present form of catalysis (sulfide/light) is thought to be unprecedented and provides a new means of preparation for organoboranes without heavy metal contamination in the products, which is highly desired in the preparation of drugs and electronic materials.
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