期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 51, 页码 18589-18593出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201503644
关键词
allylation; amino acids; cross-coupling; homogeneous catalysis; photocatalysis
资金
- National Science Foundation [CHE-1465172]
- NIH Shared Instrumentation Grant [S10OD016360, S10RR024664]
- NSF Major Research Instrumentation Grant [0320648]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1465172] Funding Source: National Science Foundation
The room temperature radical decarboxylative allylation of N-protected alpha-amino acids and esters has been accomplished via a combination of palladium and photoredox catalysis to provide homoallylic amines. Mechanistic investigations revealed that the stability of the alpha-amino radical, which is formed by decarboxylation, dictates the predominant reaction pathway between competing mechanisms.
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