期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 30, 页码 10763-10770出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501217
关键词
carbon nanotubes; click chemistry; copper nanoparticles; graphene; heterogeneous catalysis
资金
- European Union [313978]
- [DFG-BI 1337/8-1]
- [DFG-BI 1337/8-2]
- [SPP 1568]
- [SFB TRR 102]
Highly disperse copper nanoparticles immobilized on carbon nanomaterials (CNMs; graphene/carbon nanotubes) were prepared and used as a recyclable and reusable catalyst to achieve Cu-I-catalyzed [3+2] cycloaddition click chemistry. Carbon nanomaterials with immobilized N-heterocyclic carbene (NHC)-Cu complexes prepared from an imidazolium-based carbene and Cu-I show excellent stability including high efficiency at low catalyst loading. The catalytic performance evaluated in solution and in bulk shows that both types of Cu-CNMs can function as an effective recyclable catalysts (more than 10cycles) for click reactions without decomposition and the use of external additives.
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