期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 33, 页码 11712-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501353
关键词
cucurbituril; cyclodextrins; host-guest systems; rotaxanes; supramolecular chemistry
资金
- internal funding agency of Tomas Bata University in Zlin [IGA/FT/2015/005]
- program Projects of Large Infrastructure for Research, Development, and Innovations [LM2010005]
Bisimidazolium salts with one central biphenyl binding site and two terminal adamantyl binding sites form water-soluble binary or ternary aggregates with cucurbit[7]uril (CB7) and -cyclodextrin (-CD) with rotaxane and pseudorotaxane architectures. The observed arrangements result from cooperation of the supramolecular stopper binding strength and steric barriers against free slippage of the CB7 and -CD host molecules over the bisimidazolium guest axle.
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