期刊
ORGANOMETALLICS
卷 35, 期 15, 页码 2563-2566出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00468
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资金
- JSPS KAKENHI [2408, JP24109012]
- JSPS [26288019]
- Research Grants Council of Hong Kong [HKUST603313, N_HKUST603/15]
- JST [CREST 14529307]
- Science Research Promotion Fund
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [24109012, 26288019] Funding Source: KAKEN
An unsymmetrical diborane(4), pinB-BMes(2), reacted with 2,6-dimethylphenyl isocyanide to give a spirocyclic 1,2-oxaboretane or isocyanidecoordinated boraalkene. The former product formed via ring contraction of the pinacolatoboryl group. DFT calculations revealed the ring contraction proceeded via a carbocationic intermediate. This new degradation pathway from the Bpin group would provide important information in Bpin-related chemistry.
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