期刊
ORGANOMETALLICS
卷 36, 期 1, 页码 22-25出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00645
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资金
- EPSRC [EP/M024210, EP/K035908, EP/K035681]
- Engineering and Physical Sciences Research Council [EP/M024210/1, EP/K035908/1] Funding Source: researchfish
- EPSRC [EP/M024210/1, EP/K035908/1] Funding Source: UKRI
Addition of H-2 to the precursor [Rh(Cyp(2)PCH(2)CH(2)PCyp(2))(eta(2):eta(2)-C7H8)][BAr4F] gives the sigma-alkane complex [Rh(Cyp(2)PCH(2)CH(2)PCyp(2))(eta(2):eta(2)-C7H12)][BAr4F] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L-2)}(+) fragment is revealed.
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