期刊
ORGANIC LETTERS
卷 18, 期 6, 页码 1398-1401出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00335
关键词
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资金
- National Basic Research Program of China (973 Program) [2013CBA01602, 2012CB933404]
- National Natural Science Foundation of China [21574080, 21102091, 21504057]
- Shanghai Committee of Science and Technology [15JC1490500]
- Merck KGaA
A series of novel chromophores fused with multiple boron cores have been successfully synthesized by the complexation of three difluoroboryl or diphenylboryl at the periphery of 5,11,17-triazatrinaphthylene derivative ligands. Their sterically congested molecular scaffolds with expanded x-conjugated discotic backbones render them with unique electronic properties including large Stokes shifts, tunable electrochemical behaviors, and low-lying LUMO energy levels up to -3.18 eV.
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