期刊
ORGANIC LETTERS
卷 18, 期 22, 页码 5960-5963出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03111
关键词
-
资金
- Chinese NSF [81430080, 81373277]
- Major State Basic Research Development Program [2015CB910603]
- Program of Shanghai Subject Chief Scientist [16XD1404600]
A novel and efficient approach for the C(sp(2))-H bond carbonylation of benzamides has been developed using stable and inexpensive Co(OAc)(2).4H(2)O as the catalyst and the commercially available and easily handling azodicarboxylates as the nontoxic carbonyl source. A broad range of substrates bearing diverse functional groups were tolerated. This is the first example where cobalt-catalyzed C(sp(2))-H bond carbonylation occurs with azodicarboxylate as the carbonyl source.
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