期刊
ORGANIC LETTERS
卷 18, 期 15, 页码 3802-3805出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01806
关键词
-
资金
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- National Natural Science Foundation of China [21525208, 21272231]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17020300]
Co(III)-catalyzed mild C-C couplings of arenes with strained rings such as 7-oxabenzonorbomadienes and 2-vinyloxirane have been realized. The transformation is proposed to undergo ortho C-H activation, olefin insertion, and subsequent beta-oxygen elimination. A broad range of synthetically useful functional groups are compatible, thus providing a new entry to access diversely 2-functionalized indoles.
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