期刊
ORGANIC LETTERS
卷 18, 期 20, 页码 5388-5391出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02767
关键词
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资金
- 973 project [2015CB856600]
- NSFC [21272221, 21472179, 21622206, 21421091]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Fundamental Research Funds for the Central Universities [WK 2060190028, 2060190026]
A total synthesis of the highly strained natural product aquatolide has been achieved. The synthesis featured a photoinduced Wolff ring contraction reaction for the construction of bicyclo[2.1.1]hexane from diazo compound with a bicydo[2.2.1]heptane skeleton. The eight-membered enone was built by a late-stage intramolecular Nozaki-Hiyama-Kishi vinylation reaction of steric bulky vinyl iodide and aldehyde.
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