期刊
ORGANIC LETTERS
卷 18, 期 24, 页码 6324-6327出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03213
关键词
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资金
- University of Toronto
- Alphora Research, Inc.
- Natural Sciences and Engineering Research Council (NSERC)
- Ontario Graduate Scholarship
A palladium-catalyzed spirocyclization forming spirooxindoles and spirodihydrobenzofurans has been achieved. Mechanistic studies suggest that the transformation proceeds through sequential carbopalladation, C-H activation, and benzyne insertion. Both classes of spirocycles have been synthesized in good to excellent yields, and the procedure is readily scalable.
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