期刊
ORGANIC LETTERS
卷 18, 期 21, 页码 5636-5639出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02878
关键词
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资金
- U.S. Department of Health and Human Services (National Institute of General Medical Sciences) [GM65597]
- U.S. Department of Health and Human Services (National Cancer Institute) [CA76497]
- NIH Shared Instrumentation Grant Program [S10OD011952]
Benzynes produced by the thermal cycloisomerization of tetrayne substrates [i.e., by the hexadehydro-Diels-Alder (HDDA) reaction] react with perylenes to produce novel naphthoperylene derivatives. Cyclic voltammetry and absorption and emission properties of these compounds are described. DFT studies shed additional light on the dearomatization that accompanies the reaction as well as some of the spectroscopic behavior.
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