期刊
ORGANIC LETTERS
卷 18, 期 19, 页码 5130-5133出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02580
关键词
-
资金
- National Natural Science Foundation of China [21421002, 21332010, 21272036]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20020000]
A new application of trifluoromethylating reagent, methyl fluorosulfonyldifluoroacetate (FO2SCF2CO2Me, Chen's reagent), as the carbomethoxydifluoromethylating reagent under visible light photoredox conditions is reported. The visible-light induced reaction of FO2SCF2CO2Me with unactivated alkenes, styrenes, or heteroarenes affords a variety of carbomethoxydifluoromethylated products.
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