期刊
ORGANIC LETTERS
卷 18, 期 17, 页码 4166-4169出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02249
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Toronto
- Alphora Research Inc.
- NSERC
- China Scholarship Council
A palladium-catalyzed, norbornene-mediated tandem amination/cyanation reaction via Catellani-type C-H functionalization was developed using N-benzoyloxyamines as the amination reagent and Zn(CN)(2) as the terminating agent. This transformation, in which one C-N bond and one C-C bond are formed, provides an efficient approach for the synthesis of ortho-aminated benzonitriles in one pot from easily accessible starting materials.
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