期刊
ORGANIC LETTERS
卷 18, 期 16, 页码 3992-3995出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01801
关键词
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资金
- ERATO Program of JST
- MEXT [16K05771]
- US NSF [CHE-9800711]
- JSPS Fellowship for Young Scientists [14J10460]
- World Premier International Research Center (WPI) Initiative, Japan
- Grants-in-Aid for Scientific Research [14J10460, 16K05771] Funding Source: KAKEN
Two distinct structural elements that render pi -systems nonplanar, i.e., geodesic curvature and helical motifs, have been combined into new polyarenes that contain both features. The resultant corannulene-[n]helicenes (n = 5, 6) show unique molecular dynamics in their enantioinerization processes, including inversion motions of both the bowl and the helix. Optical resolution of a corannulene-based skeletally chiral molecule was also achieved for the first time, and the influence of the bowl-motif annulation on the chiroptical properties was investigated.
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