期刊
ORGANIC LETTERS
卷 18, 期 19, 页码 5162-5165出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02636
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资金
- Ecole Polytechnique
- Universite Catholique de Louvain (UCL)
- FNRS (FRIA)
A new method for the synthesis of trifluoromethyl-allenes from easily accessible a-trifluoromethyl-propargyl benzyl ether derivatives following a gold-catalyzed intramolecular hydride transfer has been developed. Various di- and trisubstituted trifluoromethyl-allenes were obtained in good to excellent yields.
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