期刊
ORGANIC LETTERS
卷 18, 期 6, 页码 1422-1425出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00352
关键词
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The copper-catalyzed regioselective intermolecular hydroamination of the aryl and trifluoromethyl group or electron-withdrawing group substituted internal alkynes with amines has been accomplished. The reaction was effectively catalyzed by the ligand-free Cu(OTf)(2) and afforded the intended amine derivatives in good yields after treatment of NaBH3CN.
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