期刊
ORGANIC LETTERS
卷 18, 期 7, 页码 1610-1613出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00464
关键词
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Functionalized polycyclic aminopyridines are central to the chemical sciences, but their syntheses are still hampered by a number of shortcomings. These nitrogenated heterocycles can be efficiently prepared by an intramolecular inverse electron demand hetero Diels-Alder (ihDA) cycloaddition of ynamides to pyrimidines. This ihDA/rDA sequence is general in scope and affords expedient access to novel types of aminopyridinyl scaffolds that hold great promise in terms of exit vector patterns.
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