期刊
ORGANIC LETTERS
卷 18, 期 4, 页码 796-799出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00058
关键词
-
资金
- Rutgers University
- NSF-MRI grant [CHE-1229030]
The first C-H bond functionalization with amides as the coupling partners via selective activation of the amide N-C bond using rhodium(I) catalysts under highly chemoselective conditions is reported. Notably, this report constitutes the first catalytic activation of the amide N-C(O) bond by rhodium. We expect that this concept will have broad implications for using amides as coupling partners for C-H activation beyond the work described herein.
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