期刊
ORGANIC LETTERS
卷 18, 期 11, 页码 2576-2579出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00918
关键词
-
资金
- Koheleth private foundation
alpha-Arylalkenes and trialkyl-substituted alkenes undergo carboxylation with CO2 in the presence of EtAlCl2 and 2,6-dibromopyridine to, afford the corresponding alpha,beta- and/or beta,gamma-unsatt,urated. Carboxylic acids. This reaction is suggested to proceed via the, electrophilic substitution of EtAlCl2 with the aid of the base, followed by the carbonation of the, resulting ate complex. This reaction can be applied to terminal dialkylalkenes by rising a mixture of 2,6-di-tert-butylpyridine and 2,6-dibromopyridine.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据