期刊
ORGANIC LETTERS
卷 18, 期 15, 页码 3870-3873出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01878
关键词
-
资金
- NIH [R15GM109288]
- NSF [CHE0647129, CHE1111192]
- MSGC fellowship
By use of 1,3-dithian-2-yl-methoxycarbonyl (Dmoc) as a protecting group and linker for oligodeoxynucleotide (ODN) synthesis, deprotection and cleavage are achieved under non-nucleophilic oxidative conditions. The nucleophile-sensitive thioester and alpha-chloroacetyl groups are conveniently incorporated into ODN sequences. The technology could be universally useful for electrophilic ODN synthesis.
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