期刊
ORGANIC LETTERS
卷 18, 期 17, 页码 4230-4233出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01964
关键词
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资金
- MEXT [16K080162]
- AMED
- JSPS [16J04480]
- Grants-in-Aid for Scientific Research [16J04480, 16K08162] Funding Source: KAKEN
The chemoselective oxidation of a-hydroxy acids to alpha-keto acids catalyzed by 2-azaadamantane N-oxyl (AZADO), a nitroxyl radical catalyst, is described. Although alpha-keto acids are labile and can easily release CO2 under oxidation conditions, the use of molecular oxygen as a cooxidant enables the desired chemoselective oxidation.
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