期刊
ORGANIC LETTERS
卷 18, 期 16, 页码 4012-4015出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01837
关键词
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资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21520102003, 21272180, 21302148]
- Hubei Province Natural Science Foundation of China [2013CFA081]
- Research Fund for the Doctoral Program of Higher Education of China [2015M580665, 2016T90720]
- Ministry of Science and Technology of China [2012YQ120060]
- Program of Introducing Talents of Discipline to Universities of China (111 Program)
Reductive cross-coupling has emerged, as a direct method for the construction of carbon carbon bonds. Most cobalt-, nickel-, and palladium-catalyzed reductive cross-coupling reactions to date are limited to stoichiometric Mn(0) or Zn(0) as the reductant. One nickel-catalyzed cross-coupling paradigm using Et3N as the terminal reductant is reported. By using this photoredox catalysis and nickel catalysis approach, a direct Csp(2)-Csp(3) reductive cross coupling of aryl bromides with alkyl bromides is achieved under mild conditions without stoichiometric metal reductants.
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