期刊
ORGANIC LETTERS
卷 18, 期 24, 页码 6292-6295出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03156
关键词
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资金
- ICIQ Foundation
- MINECO/FEDER [CTQ2015-69136-R]
- DEC Generalitat de Catalunya [2014SGR827]
A set of six solid-supported diarylprolinol catalysts (varying on the anchoring strategy and the type of polymeric support) has been prepared and applied to the enantioselective cyclopropanation reaction. The selected candidate allows implementation of a long flow experiment (48 h) and generates a library of 12 cyclopropanes by sequential flow experiments. The mildness and utility of the method have enabled a telescoped process in which the outstream is directly used in a Wittig flow reaction.
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