期刊
ORGANIC LETTERS
卷 18, 期 22, 页码 5880-5883出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02959
关键词
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资金
- European Union
- European Commission
- FAPESP [2014/16516-9]
- People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme (FP7)
A new method for the stereoselective metal-free syn-dihydroxylation of electron-rich olefins is reported, involving reaction with TEMPO/IBX in trifluoroethanol (TFE) or hexafluoroisopropanol (HFIP) and the addition of a suitable nucleophile. Orthogonally protected syn 1,2-diols were obtained with high levels of diastereocontrol, and these products were selectively deprotected and selectively functionalized into synthetically useful compounds.
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