期刊
ORGANIC LETTERS
卷 18, 期 4, 页码 696-699出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03666
关键词
-
资金
- MEXT, Japan
- Grants-in-Aid for Scientific Research [16H06384] Funding Source: KAKEN
A novel approach to chiral anti-alpha,beta-diamino acid derivatives through tandem orthogonal organocatalysis has been developed. Chiral phosphoric acid catalysts control the chemo-, regio-, and stereoselective addition of hydroxylamines to alkylideneoxazolones, while a phosphine catalyst promotes the isomerization of Z-alkylideneoxazolones to the more reactive E- alkylideneoxazolones.
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