期刊
ORGANIC LETTERS
卷 18, 期 24, 页码 6232-6235出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02710
关键词
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资金
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21472051, 21420102003, 21490572]
- Pearl River S&T Nova Program of Guangzhou [201610010160]
The vinyl moiety-assisted selective O-nucleopalladation is reported, which offers rapid constructions of cycloolefins and cyclopropanes via oxidant-induced cyclization of enynes. O-2 resulted in the unexpected 6-endo-Heck cyclization, while CuCl2 led to a 5-exo-trig pathway and synergetic S(N)2-type C-C bond formation. Amide works as an O-transferred nucleophilic group to activate the alkyne moiety, which induced divergent annulation processes. Moreover, the regenerated amides could be used for further modifications.
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