期刊
ORGANIC LETTERS
卷 18, 期 21, 页码 5652-5655出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02893
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资金
- MINECO (Gobierno de Espana) [CTQ2013-47494-P]
- MINECO
An efficient organocatalytic asymmetric synthesis of alpha-hydroxyketones has been developed. Quinine-derived thiourea catalyzed the enantioselective Friedel Crafts alkylation of naphthols and activated phenols with aryl- and alkylglyoxal hydrates, providing the corresponding chiral alpha-hydroxyketones with high yields (up to 97%) and excellent enantioselectivities (up to 99% ee).
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