期刊
ORGANIC LETTERS
卷 18, 期 8, 页码 1840-1843出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00577
关键词
-
资金
- NSERC
Dimethylamine and 2,4,6-triformylphloroglucinol react to form a product with a highly contorted nonplanar geometry due to favorable electron delocalization. This new heteroradialene compound has been studied by X-ray diffraction, variable-temperature multinuclear NMR spectroscopy, IR spectroscopy, UV-vis spectroscopy, and ab initio calculations. Electron delocalization throughout the periphery of the central ring leads to a structure that retains very little of the aromatic characteristics of the starting material.
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