期刊
ORGANIC LETTERS
卷 18, 期 7, 页码 1642-1645出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00503
关键词
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资金
- JSPS [26810060]
- Program for Promoting the Enhancement of Research Universities from MEXT
- Okayama University
- ACT-C, JST
- Grants-in-Aid for Scientific Research [26810060] Funding Source: KAKEN
Palladium-catalyzed carbothiolation of terminal alkynes with azolyl sulfides affords various 2-(azolyl)alkenyl sulfides with perfect regio- and stereoselectivities. The present addition reaction proceeded through a direct cleavage of carbon-sulfur bonds in azolyl sulfides. The resulting adducts that are useful intermediates in organic synthesis are further transformed to multisubstituted olefins containing azolyl moieties.
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