期刊
ORGANIC LETTERS
卷 18, 期 10, 页码 2359-2362出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00789
关键词
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资金
- JSPS KAKENHI, Platform for Drug Discovery, Informatics, and Structural Life Science from the Ministry of Education, Culture, Sports, Science and Technology, Japan [25221301, 26713001]
- JSPS
- Grants-in-Aid for Scientific Research [26713001] Funding Source: KAKEN
The total synthesis of (-)-cardiopetaline, an aconitine-type natural product, has been accomplished. Our synthesis involved a Wagner-Meerwein rearrangement of a sulfonyloxirane that enabled, in a single step, the construction of the bicyclo[3.2.1] system in the aconitine skeleton and effective introduction of oxygen functional groups at the appropriate positions.
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