期刊
ORGANIC LETTERS
卷 18, 期 9, 页码 2228-2231出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00864
关键词
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资金
- National Natural Science Foundation of China [21302193, 21572236]
- Natural Science Foundation of Yunnan Province [2014FA008, 2015FB167]
- Yunnan High-End Technology Professionals Introduction Program [2010CI117]
- program for changjiang scholars and innovative research team in university [IRT13095]
A Curtius-like rearrangement of hydroxamates to isocyanates was discovered. This reaction was initiated from an iron(II)-nitrenoid complex, which was generated by the iron(II)-catalyzed cleavage of N-O bonds of functionalized hydroxamates. To demonstrate the efficiency of this new Curtius-like rearrangement in synthetic chemistry, a biomimetic strategy for the one-pot preparation of bisindolylmethanes was developed.
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