期刊
ORGANIC LETTERS
卷 18, 期 12, 页码 2962-2965出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01301
关键词
-
资金
- National Natural Science Foundation of China [21472084, 81421091]
- Qing Lan Project of Jiangsu Province
An electron-donor acceptor (EDA) complex between Togni's reagent and a tertiary amine has been introduced. The existence of this EDA complex was supported by NMR titration experiments. The hydrotrifluoromethylation of unactivated aliphatic alkenes and alkynes enabled by this EDA complex has also been developed. This hydrotrifluoromethylation protocol is operationally simple and, promoted by a tertiary amine.
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