期刊
ORGANIC LETTERS
卷 18, 期 14, 页码 3326-3329出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01371
关键词
-
资金
- China NSFC [21272047, 21372055, 21472030]
- SKLUWRE [2015DX01]
- Fundamental Research Funds for the Central Universities [HIT.BRETIV.201310]
A transition-metal-free approach was disclosed for intermolecular aryl C-N bonds formation between phenols and cyclic anilines via cross-dehydrogenative coupling (CDC) amination that was mediated by visible light, wherein K2S2O8 served as an external oxidant. The salient features of this protocol include circumventing the requirement for prefunctionalized starting materials and achieving single regioselectivity of amination adducts at room temperature.
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