期刊
ORGANIC LETTERS
卷 18, 期 9, 页码 2098-2101出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00722
关键词
-
资金
- European Research Council (ERC) [306793 - CASAA]
Silicon amine protocol (SLAP) reagents for photocatalytic cross-coupling with aldehydes and ketones to form N-unprotected piperazines have been developed. This blue light promoted process tolerates a wide range of heteroaromatic, aromatic, and aliphatic aldehydes and structurally and stereochemically complex SLAP reagents. It provides a tin-free alternative to SnAP (tin amine protocol) reagents for the synthesis of substituted piperazines.
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