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ORGANIC LETTERS
卷 18, 期 18, 页码 4494-4497出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02031
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资金
- RFBR [16-33-60012 mol_a_dk]
An efficient (one- and two-step) synthesis of trifluoromethylated derivatives of the natural alkaloids nazlinine, trypargine, and homotrypargine was elaborated. Trifluoromethyl-substituted 5-7-membered cyclic imines were used as a masked carbonyl component in the Pictet-Spengler reaction with various tryptamines. As a result, this approach opens access to a family of alkaloid-like compounds bearing a CF3 group at position 1 of tetrahydro-beta-carboline.
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