期刊
ORGANIC LETTERS
卷 18, 期 5, 页码 912-915出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03579
关键词
-
资金
- Ministry of Education of the People's Republic of China (Program for Changjiang Scholars and Innovative Research Team in University) [IRT13095]
- Natural Science Foundation of China [NSFC 21162032]
A method for conducting selenium-promoted intermolecular Friedel-Crafts (F-C) alkylation reactions has been developed with simple alkenes using trimethylsilyl trifluoromethane-sulfonate as a catalyst and N-phenylselenophthalimide as an efficient selenium source. Electron-rich arenes smoothly underwent F-C alkylation with a variety of alkenes to afford alkylated products in good yield and with high regioselectivity and diastereoselectivity. The regioselectivity and stereoselectivity of arenes and alkenes as well as a preliminary mechanism of the F-C alkylation reaction are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据