期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 40, 页码 9456-9465出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01774f
关键词
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资金
- National Natural Science Foundation of China [21272191, 21572186]
- Natural Science Foundation of Fujian Province for Distinguished Young Scholars [2015J06003]
- President Research Funds from Xiamen University [20720150045]
N-Containing tricyclic compounds, especially the tricyclic N-heterocycles, are important structural motifs that possess significant potential in organic chemistry for their momentous applications in natural and man-made bioactive molecules. Gold catalysis, which exhibits specific catalytic properties in terms of both high reactivity and selectivity for various organic transformations, has proven to be a powerful tool for the straightforward synthesis of cyclic compounds, especially the polycyclic molecules. Currently, several approaches towards polycycle synthesis have been developed via gold-catalyzed transformations of readily available ynamides. In this review, we will focus on the recent advances in the gold-catalyzed construction of N-containing tricycles based on ynamides by highlighting their specificity and applicability, and the mechanistic rationale is presented where possible.
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