期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 11, 页码 3016-3021出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00169f
关键词
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资金
- National Natural Science Foundation of China [21376058, 21302171]
- Changjiang Scholars and Innovative Research Team in Chinese University [IRT 1231]
- Zhejiang Provincial Natural Science Foundation of China [LZ13B020001]
A simple and mild protocol for copper catalyzed halogenation of quinoline at C5 and C7 positions was developed, affording the desired remote C-H activation products in moderate to good yields. This reaction proceeds with low-cost sodium halides (NaX, X = Cl, Br, I) and features excellent substrate tolerance. A series of control experiments were carried out to illustrate a single-electron-transfer process which plays a vital role in the halogenation.
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