期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 32, 页码 7702-7706出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01161f
关键词
-
资金
- DFG [NA-686/8, SPP 1807]
The host-guest chemistry of large-ring cyclodextrins (LRCDs) has been largely unexplored due to the lack of suitable guest molecules that bind with significant affinities to enable potential applications. Herein, we report their complexation with dodecaborate anions (B(12)X12(2-)), a novel class of guest molecules. The binding constants of the inorganic guests (10(4)-10(6) M-1) allow their classification as the first tight binders for LRCDs.
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