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Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 33, 页码 7829-7831

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00797j

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资金

  1. National Science Foundation of China [21272096, 21472080]
  2. Program for Changjiang Scholars and the Innovative Research Team in University [PCSIRT: IRT15R28]
  3. Fundamental Research Funds for the Central Universities [lzujbky-2016-50, lzujbky-2016-ct02]

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As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.

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