期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 12, 页码 3246-3255出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00210b
关键词
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资金
- Science and Engineering Research Board [SR/S1/OC-55/2011]
- Council of Scientific and Industrial Research [02(0088)/12/EMR-II]
- Ministry of Human Resource Development (CoE/FAST)
Iron-catalyzed dioxygenation of alkenes in air using N-hydroxyphthalimide (NHPI) and N-hydroxybenzotriazole (HOBt) is described at room temperature. The products can be readily converted into 1,2-vicinal diols using PPh3 and Mo(CO)(6). The use of Fe(NO3)(3)center dot 9H(2)O as the catalyst, mild reaction conditions and the selectivity are the significant practical features. The radical scavenger experiment suggests that the reaction proceeds via a radical intermediate. The synthetic and mechanistic aspects have been presented.
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