期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 40, 页码 9451-9455出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01660j
关键词
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资金
- NSFC [21672169, 61605158]
- 1000 Youth Talents Plan
- Science and Technology Department of Shaanxi Province [2016JQ2028]
- Education Department of Shaanxi Province [16JK1790]
The development of new methods for the rapid assembly of spirocyclic frameworks with high molecular complexity is always of great importance for organic syntheses. In this perspective, we endeavour to cover the recent achievements from our group in the construction of synthetically valuable spirocyclohexadienones from easily accessible phenol-derived biaryls using a transition-metal-catalyzed C-H activation/dearomatization strategy. The key feature of these cooperative reactions is the simultaneous C-H bond activation and aromaticity disruption, leading to the formation of various spirocyclic molecules that are difficult or inaccessible using conventional approaches.
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