期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 29, 页码 7084-7091出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01308b
关键词
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资金
- Carl Zeiss foundation
3,5-Dialkyl indolizidines have been prepared in four linear steps from commercially available starting materials. The sequence involves two direct alpha-functionalization steps and a subsequent reductive amination and provides diastereoselective access to both C-3 epimers of the 5,9-trans-substituted indolizines. The naturally occurring indolizidines 195B and 223AB have been synthesized using this methodology.
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