期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 16, 页码 3873-3877出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00512h
关键词
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资金
- FCT (Fundacao para a Ciencia e a Tecnologia) [UID/CTM/50011/2013, POCI-01-0145-FEDER-007679]
- FCT/MEC
- FEDER (Fundo Europeu de Desenvolvimento Regional)
- FEDER through COMPETE (Programa Operacional Factores de Competitividade)
- FCT [FCOMP-01-0124-FEDER-029779, PTDC/QEQ-SUP/1906/2012, BPD/UI89/4864/2014]
- FCT - MCTES [SFRH/BPD/46473/2008, SFRH/BPD/89068/2012]
- European Union - MCTES [SFRH/BPD/46473/2008, SFRH/BPD/89068/2012]
- European Social Fund through the program POPH of QREN
- Fundação para a Ciência e a Tecnologia [UID/CTM/50011/2013, PTDC/QEQ-SUP/1906/2012] Funding Source: FCT
Metal-free cucurbit[7]uril (CB7) solid-state assemblies promote acid-catalysed alcoholysis of aliphatic and aromatic epoxides under mild conditions to give beta-alkoxy alcohols, which are important intermediates for the synthesis of a vast range of compounds such as bioactive pharmaceuticals. The catalytic process is heterogeneous and the catalyst can be reused in consecutive runs without any reactivation treatment. The acid species responsible for the catalytic activity of CB7 may be entrapped hydronium ions.
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