期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 11, 页码 3027-3030出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00295a
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资金
- CSIR, New Delhi
- DST, New Delhi [SR/S1/OC-67/2010]
An unprecedented synthesis of novel 3-azido indoles has been developed using I-2 and NaN3 in high yields and excellent regio-selectivity. The reaction proceeds under metal-free conditions at room temperature. Essentially, an umpolung in reactivity at the C-3 position of indole has been achieved by the activation of indoles with I-2.
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