期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 29, 页码 6942-6946出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01226d
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资金
- Research Committee of Aristotle University of Thessaloniki
- Pharmathen SA
A common enyne scaffold, resembling the structures of natural elemanes was found to be an excellent substrate for highly regioselective cycloisomerizations to produce diverse cyclopropane sesquiterpenoids. Platinum-catalysis was utilized to produce either lindenane or myliol cores, found in natural products, starting from enyne acetate 10 and its corresponding allene 12 respectively. Based on this concept, a second generation strategy allows the formal synthesis of sarcandralactone A.
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