期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 14, 期 24, 页码 5520-5524出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00073h
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资金
- UCSB
- National Science and Engineering Research Council of Canada (NSERC)
A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso-oxidative aromatic substitution (iSOAr) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quionone monoketals has also been investigated and a predictive model has been established.
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