期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 21, 期 30, 页码 10666-10670出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501692
关键词
covalent organic frameworks; ink-jet printing; porous crystalline materials; processability; soft-lithography
资金
- MINECO (Spain) [MAT2013-46753-C2-1-P, MAT2012-30994, MAT2014-52305-P]
- UCM
- ICREA Funding Source: Custom
We report herein an efficient, fast, and simple synthesis of an imine-based covalent organic framework (COF) at room temperature (hereafter, RT-COF-1). RT-COF-1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N-2 and CO2. The room-temperature synthesis has enabled us to fabricate and position low-cost micro- and submicropatterns of RT-COF-1 on several surfaces, including solid SiO2 substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink-jet printing.
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